Investigation of copper(II) tetrafluoroborate catalysed epoxide opening

We report the extension of the copper(II) tetrafluoroborate catalysed opening of epoxides with alcohols to include a wider variety of alcohols, a range of solvents and a method to purify the products from the reaction.

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Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 2011-12, Vol.52 (52), p.7091-7094
Hauptverfasser:	Capes, Amy S., Crossman, Arthur T., Webster, Lauren A., Ferguson, Michael A.J., Gilbert, Ian H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids chemical reactions chemical structure Chemistry Copper(II) tetrafluoroborate Epoxide epoxides Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Lewis acid Organic chemistry Preparations and properties Solvents Tetrahedrons
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Beschreibung
Zusammenfassung:	We report the extension of the copper(II) tetrafluoroborate catalysed opening of epoxides with alcohols to include a wider variety of alcohols, a range of solvents and a method to purify the products from the reaction.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.10.090