20,23,26,29,32,35,38,41-Octa-oxa-5,9,13-triaza-penta-cyclo-[15.14.10.1.1.1]tetra-tetra-conta-1,3(42),7,9,11(44),15(43),16,18,30-nona-ene-6,12-dione acetone mono-solvate

20,23,26,29,32,35,38,41-Octa-oxa-5,9,13-triaza-penta-cyclo-[15.14.10.1.1.1]tetra-tetra-conta-1,3(42),7,9,11(44),15(43),16,18,30-nona-ene-6,12-dione acetone mono-solvate

In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol-ecule is encapsulated into the cavity of the cryptand and fixed by two N-H⋯O and one C-H⋯O hydrogen bond. C-H⋯O and C-H⋯N inter-actions link neighbouring cryptands. The dihedral angles between the pyridine...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-01, Vol.68 (Pt 1), p.o107-o107
Hauptverfasser: Pan, Shaowu, Yang, Dengke, Yang, Yu, Jiang, Lasheng
Format: Artikel
Sprache:eng
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Organic Papers
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Zusammenfassung:In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol-ecule is encapsulated into the cavity of the cryptand and fixed by two N-H⋯O and one C-H⋯O hydrogen bond. C-H⋯O and C-H⋯N inter-actions link neighbouring cryptands. The dihedral angles between the pyridine ring and the benzene rings are 86.47 (17) and 85.53 (13)°.
ISSN:1600-5368
DOI:10.1107/S1600536811051877