Tetra-aqua-bis-[4-(4H-1,2,4-triazol-4-yl)benzoato-κN]manganese(II) deca-hydrate

In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol-ecules in a distorted octa-hedral geometry. The Mn(II) ion and two coordinated water mol-ecules lie on a twofold rota...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-08, Vol.67 (Pt 8), p.m1072-m1072
Hauptverfasser: Piao, Ying-Ai, Xuan, Zhen-Yu
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol-ecules in a distorted octa-hedral geometry. The Mn(II) ion and two coordinated water mol-ecules lie on a twofold rotation axis. The water mol-ecules are involved in O-H⋯N and O-H⋯O hydrogen bonds with the triazole N atoms and carboxyl-ate O atoms, yielding a three-dimensional supra-molecular network. π-π inter-actions between the benzene rings [centroid-centroid distance = 3.836 (9) Å] are observed.
ISSN:1600-5368
DOI:10.1107/S1600536811025335