Dicaesium diaqua-bis-(methyl-ene-diphospho-nato-κO,O')cobaltate(II)

Dicaesium diaqua-bis-(methyl-ene-diphospho-nato-κO,O')cobaltate(II)

The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl-enediphospho-nate ligand and one water mol-ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystall...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-10, Vol.67 (Pt 10), p.m1354-m1354
Hauptverfasser: van Merwe, Kina, Visser, Hendrik G, Venter, Johan A
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
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Zusammenfassung:The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl-enediphospho-nate ligand and one water mol-ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octa-hedrally coordinated by six O atoms with Cs-O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O-H⋯O hydrogen bonds.
ISSN:1600-5368
DOI:10.1107/S1600536811035355