N,N'-Bis(3-chloro-phen-yl)malonamide
The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol-ecules. In both independent mol-ecules, the N-H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-09, Vol.67 (Pt 9), p.o2278-o2278 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2), contains two independent mol-ecules. In both independent mol-ecules, the N-H bond in one of the amide fragments is anti to the meta-chloro group of the adjacent benzene ring and that in the other amide group is syn to the other meta-chloro group. Furthermore, in both mol-ecules, each amide group is almost coplanar with the adjacent phenyl ring, making dihedral angles of 10.5 (2) and 8.7 (2)° in one molecule and 9.0 (2) and 9.6 (2)° in the other. The planes of the amide groups are inclined at dihedral angles of 83.4 (1) and 87.4 (1)° in the two mol-ecules. In the crystal, mol-ecules are linked into a chain by inter-molecular N-H⋯O hydrogen bonds. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536811031333 |