Catalytic Enantioselective Conjugate Allylation of Unsaturated Methylidene Ketones

Catalytic Enantioselective Conjugate Allylation of Unsaturated Methylidene Ketones

The use of unsaturated methylidene ketones in catalytic conjugate allylations allows a significant expansion in substrate scope and, with appropriate chiral ligands, occurs in a highly enantioselective fashion.

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2011-03, Vol.13 (5), p.995-997
Hauptverfasser: Brozek, Laura A, Sieber, Joshua D, Morken, James P
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemical synthesis
Alkenes - chemistry
Catalysis
Combinatorial Chemistry Techniques
Ketones - chemical synthesis
Ketones - chemistry
Ligands
Molecular Structure
Stereoisomerism
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Zusammenfassung:The use of unsaturated methylidene ketones in catalytic conjugate allylations allows a significant expansion in substrate scope and, with appropriate chiral ligands, occurs in a highly enantioselective fashion.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol102982b