(E)-N'-(3,3-Dimethyl-2,6-diphenyl-piperidin-4-yl-idene)isonicotinohydrazide
In the title mol-ecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridine-ring and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-10, Vol.66 (Pt 11), p.o2841-o2841 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title mol-ecule, C(25)H(26)N(4)O, the piperidine ring adopts a chair conformation, with the plane through the four coplanar atoms making dihedral angles of 84.76 (6), 82.28 (5) and 81.91 (6)° with the pyridine-ring and the phenyl rings at the 2 and 6 positions, respectively. The pyridine ring makes dihedral angles of 64.13 (8) and 10.75 (8)° with the phenyl rings at the 2 and 6 positions, respectively. The dihedral angle between the two phenyl rings is 53.57 (8)°. The phenyl rings and one of the methyl groups at position 3 have an equatorial orientation. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536810040936 |