(Z)-2-(2-Isopropyl-5-methyl-phen-oxy)-N'-(2-oxoindolin-3-yl-idene)acetohydrazide

In the title Mannich base, C(20)H(21)N(3)O(3), an isatin derivative of thymol, the O-CH(2)-C(=O)-N(H)-N fragment connect-ing the aromatic and fused-ring systems is approximately planar, with the N-N single bond in a Z configuration. The amino H atom of this N-N fragment is intra-molecularly hydrogen...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-06, Vol.66 (Pt 7), p.o1614-o1614
Hauptverfasser: Zade, Chetan M, Pete, Umesh D, Dikundwar, Amol G, Bendre, Ratnamala S
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title Mannich base, C(20)H(21)N(3)O(3), an isatin derivative of thymol, the O-CH(2)-C(=O)-N(H)-N fragment connect-ing the aromatic and fused-ring systems is approximately planar, with the N-N single bond in a Z configuration. The amino H atom of this N-N fragment is intra-molecularly hydrogen bonded to the carbonyl O atom of the indolinone fused ring as well as to the phen-oxy O atom of the aromatic ring. The amino H atom of the indoline fused ring forms a hydrogen bond with the double-bond O atom of an adjacent mol-ecule, this hydrogen bond giving rise to a linear chain motif.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810019008