Probing Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy

Probing Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy

In‐depth probing: A NRVS single‐crystal study (NRVS=nuclear resonance vibrational spectroscopy) has provided detailed information on the in‐plane modes of nitrosyl iron porphyrinate [Fe(oep)(NO)] (see picture; oep=octaethylporphyrin). The axial nitrosyl ligand controls the direction of the in‐plane...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-06, Vol.49 (26), p.4400-4404
Hauptverfasser: Pavlik, Jeffrey W, Barabanschikov, Alexander, Oliver, Allen G, Alp, E. Ercan, Sturhahn, Wolfgang, Zhao, Jiyong, Sage, J. Timothy, Scheidt, W. Robert
Format: Artikel
Sprache:eng
Schlagworte:
ANISOTROPY
Coordination Complexes - chemistry
Crystallization
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
IRON COMPLEXES
iron porphyrinates
Magnetic Resonance Spectroscopy
Metalloporphyrins - chemistry
MONOCRYSTALS
Mössbauer spectroscopy
NO complexes
NRVS (nuclear resonance vibrational spectroscopy)
PORPHYRINS
RESONANCE
SPECTROSCOPY
Vibration
VIBRATIONAL STATES
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Zusammenfassung:In‐depth probing: A NRVS single‐crystal study (NRVS=nuclear resonance vibrational spectroscopy) has provided detailed information on the in‐plane modes of nitrosyl iron porphyrinate [Fe(oep)(NO)] (see picture; oep=octaethylporphyrin). The axial nitrosyl ligand controls the direction of the in‐plane iron motion.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201000928