[1-(2-Oxidobenzylidene)-4-phenylthiosemicarbazidato-κ3 O,N 1,S](pyridine-κN)copper(II)
In the structure of the title compound, [Cu(C 14 H 11 N 3 OS)(C 5 H 5 N)], the Cu II atom exhibits a slightly distorted square-planar CuN 2 OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thioamide S atom from the tridentate thiosemicarbazonate dianion, and the N atom of...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-05, Vol.66 (Pt 6), p.m676-m676 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the structure of the title compound, [Cu(C
14
H
11
N
3
OS)(C
5
H
5
N)], the Cu
II
atom exhibits a slightly distorted square-planar CuN
2
OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thioamide S atom from the tridentate thiosemicarbazonate dianion, and the N atom of a pyridine molecule. The thiosemicarbazonate ligand exists in the thiol tautomeric form as an
E
isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H⋯S, C—H⋯O, C—H⋯N and C—H⋯S hydrogen-bonding interactions consolidates the structure. |
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ISSN: | 1600-5368 |
DOI: | 10.1107/S1600536810017381 |