[1-(2-Oxidobenzyl­idene)-4-phenyl­thio­semicarbazidato-κ3 O,N 1,S](pyridine-κN)copper(II)

In the structure of the title compound, [Cu(C 14 H 11 N 3 OS)(C 5 H 5 N)], the Cu II atom exhibits a slightly distorted square-planar CuN 2 OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio­amide S atom from the tridentate thio­semicarbazonate dianion, and the N atom of...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-05, Vol.66 (Pt 6), p.m676-m676
Hauptverfasser: Bon, Vladimir V., Orysyk, Svitlana I., Pekhnyo, Vasily I.
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Sprache:eng
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Zusammenfassung:In the structure of the title compound, [Cu(C 14 H 11 N 3 OS)(C 5 H 5 N)], the Cu II atom exhibits a slightly distorted square-planar CuN 2 OS coordination polyhedron consisting of a phenyl O, an azomethine N and a thio­amide S atom from the tridentate thio­semicarbazonate dianion, and the N atom of a pyridine mol­ecule. The thio­semicarbazonate ligand exists in the thiol tautomeric form as an E isomer. Rotational disorder of the pyridine and phenyl rings in a 1:1 ratio of the respective components is observed. An extensive network of weak N—H⋯S, C—H⋯O, C—H⋯N and C—H⋯S hydrogen-bonding inter­actions consolidates the structure.
ISSN:1600-5368
DOI:10.1107/S1600536810017381