N'-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate

N'-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate

In the title compound, C(7)H(12)N(6)O·2H(2)O, the Z configuration of the hydrazone fragment is stabilized by an intra-molecular N-H⋯N hydrogen bond involving one of the amino groups. In the crystal structure, the hydrazonamide mol-ecules are connected via inter-molecular N-H⋯O=C hydrogen bonds, form...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-04, Vol.66 (Pt 5), p.o1209-o1210
Hauptverfasser: Dolzhenko, Anna V, Dolzhenko, Anton V, Tan, Geok Kheng, Koh, Lip Lin, Pastorin, Giorgia
Format: Artikel
Sprache:eng
Schlagworte:
Organic Papers
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the title compound, C(7)H(12)N(6)O·2H(2)O, the Z configuration of the hydrazone fragment is stabilized by an intra-molecular N-H⋯N hydrogen bond involving one of the amino groups. In the crystal structure, the hydrazonamide mol-ecules are connected via inter-molecular N-H⋯O=C hydrogen bonds, forming C(7) chains running along [010]. The chains form sheets parallel to the (01). The chains are cross-linked by water mol-ecules to form a three-dimensional hydrogen-bonded network.
ISSN:1600-5368
DOI:10.1107/S1600536810015357