N,N-Bis(diphenyl-phosphino)ethyl-amine

In the title compound, C(26)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-11, Vol.65 (Pt 12), p.o3081-o3081
Hauptverfasser: Cloete, Nicoline, Visser, Hendrik G, Roodt, Andreas, Gabrielli, William F
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C(26)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached to it in order to accommodate the steric bulk of the phenyl groups and the alkyl group. The distortion of the trigonal-pyramidal geometry of the nitro-gen is further illustrated by the bond angles which range between 114.0 (1) and 123.7 (1)°. There are no classical inter-molecular inter-actions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809045978