N,N-Bis(diphenyl-phosphino)ethyl-amine
In the title compound, C(26)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-11, Vol.65 (Pt 12), p.o3081-o3081 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, C(26)H(25)NP(2), the diphenyl-phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached to it in order to accommodate the steric bulk of the phenyl groups and the alkyl group. The distortion of the trigonal-pyramidal geometry of the nitro-gen is further illustrated by the bond angles which range between 114.0 (1) and 123.7 (1)°. There are no classical inter-molecular inter-actions. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536809045978 |