6,6'-Dimeth-oxy-2,2'-[(E,E')-(4-chloro-m-phenyl-ene)bis-(nitrilo-methyl-idyne)]diphenol
The title compound, C(22)H(19)ClN(2)O(4), has the appearance of a warped butterfly. One 2-hydr-oxy-3-methoxy-benzyl-idene-amino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; howeve...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-09, Vol.65 (Pt 10), p.o2573-o2573 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The title compound, C(22)H(19)ClN(2)O(4), has the appearance of a warped butterfly. One 2-hydr-oxy-3-methoxy-benzyl-idene-amino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; however, the methoxy-phenol group is planar [with the maximum deviation of 0.033 (2) Å] and makes a dihedral angle of 41.7 (3)° with the central benzene ring. The mol-ecule is stabilized by intra-molecular O-H⋯N hydrogen bonding. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonding and C-H⋯π inter-actions. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536809037386 |