Bis(triphenyl-stann-yl) thio-phene-2,5-dicarboxyl-ate

Bis(triphenyl-stann-yl) thio-phene-2,5-dicarboxyl-ate

Mol-ecules of the title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(2)O(4)S)], lie on inversion centres with the central thio-phene ring disordered equally over two orientations. The carboxyl-ate groups are approximately coplanar with the thio-phene ring [dihedral angle = 4.0 (1)°] and the Sn-O bond distanc...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-06, Vol.65 (Pt 7), p.m722-m722
Hauptverfasser: Zhao, Lichun, Liang, Jian, Yue, Guihua, Deng, Xin, He, Ying
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
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Beschreibung
Zusammenfassung:Mol-ecules of the title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(2)O(4)S)], lie on inversion centres with the central thio-phene ring disordered equally over two orientations. The carboxyl-ate groups are approximately coplanar with the thio-phene ring [dihedral angle = 4.0 (1)°] and the Sn-O bond distance of 2.058 (4) Å is comparable to that in related organotin carboxyl-ates.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809020273