trans-Bis[1,3-bis-(2-methoxy-phen-yl)triazenido]dimethano-lcadmium(II)
In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis-(2-methoxy-phen-yl)triazene ligands and by the O atoms of two methanol mol-ecules. The distorted octa-hedral coordination geometry of the Cd atom has t...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-02, Vol.65 (Pt 3), p.m351-m351 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis-(2-methoxy-phen-yl)triazene ligands and by the O atoms of two methanol mol-ecules. The distorted octa-hedral coordination geometry of the Cd atom has two N and two O atoms in the equatorial plane, and two O atoms in axial positions. The complex is stabilized by intra-molecular O-H⋯O and O-H⋯N hydrogen bonds. In the crystal structure the complexes are linked into chains via inter-molecular C-H⋯π stacking inter-actions. One of the methanol C atoms is disordered with ouccupancies of 0.7:0.3. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S160053680900676X |