4-Amino-13-(1-naphth-yl)-[2,2]paracyclo-phane

4-Amino-13-(1-naphth-yl)-[2,2]paracyclo-phane

THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarde...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-03, Vol.64 (Pt 4), p.o650-o650
Hauptverfasser: Sun, Junshan, Huo, Yanmin, Wu, Rentao, Li, Jikun, Ma, Yudao
Format: Artikel
Sprache:eng
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Organic Papers
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Zusammenfassung:THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo-phane units are very slightly deformed from planarity as shallow boats.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808005333