Poly[hexaaquacopper(II) [di-μ3-sulfato-disodiate(I)]]
The title compound, {[Cu(H 2 O) 6 ][Na 2 (SO 4 ) 2 ]} n , has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a spe...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-01, Vol.64 (Pt 2), p.i7-i7 |
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| container_issue | Pt 2 |
| container_start_page | i7 |
| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 64 |
| creator | Wu, Wen Xie, J.-M. Xie, D.-P. Xuan, Y.-W. |
| description | The title compound, {[Cu(H
2
O)
6
][Na
2
(SO
4
)
2
]}
n
, has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (
). The Na atom is coordinated by five O atoms of four sulfates [Na—O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetradentate mode. |
| doi_str_mv | 10.1107/S1600536807067608 |
| format | Article |
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2
O)
6
][Na
2
(SO
4
)
2
]}
n
, has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (
). The Na atom is coordinated by five O atoms of four sulfates [Na—O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetradentate mode.</description><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536807067608</identifier><identifier>PMID: 21201248</identifier><language>eng</language><publisher>International Union of Crystallography</publisher><subject>Inorganic Papers</subject><ispartof>Acta crystallographica. Section E, Structure reports online, 2008-01, Vol.64 (Pt 2), p.i7-i7</ispartof><rights>International Union of Crystallography 2008 2008</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960320/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960320/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>Wu, Wen</creatorcontrib><creatorcontrib>Xie, J.-M.</creatorcontrib><creatorcontrib>Xie, D.-P.</creatorcontrib><creatorcontrib>Xuan, Y.-W.</creatorcontrib><title>Poly[hexaaquacopper(II) [di-μ3-sulfato-disodiate(I)]]</title><title>Acta crystallographica. Section E, Structure reports online</title><description>The title compound, {[Cu(H
2
O)
6
][Na
2
(SO
4
)
2
]}
n
, has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (
). The Na atom is coordinated by five O atoms of four sulfates [Na—O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetradentate mode.</description><subject>Inorganic Papers</subject><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNpjYJA0NNAzNDQw1w82NDMwMDU2szAwNzAzNzOwYGLgBAnpgsQ4GLiKi7MMDAzNzI0M2Rk4jAyNDAyNTCw4GawC8nMqozNSKxIPrU0sLAWSyfkFBalFGp6emgrRKZm65_YY6xaX5qQlluTrpmQW56dkJpakanhqxsbyMLCmJeYUp_JCaW4GOzfXEGcP3YLSpNzUlOTUvJKixJz4gqLM3MSiyvj8xMx4VJm8zIz49PyyeCNLMwNjIwNjig0AABCNVaM</recordid><startdate>20080104</startdate><enddate>20080104</enddate><creator>Wu, Wen</creator><creator>Xie, J.-M.</creator><creator>Xie, D.-P.</creator><creator>Xuan, Y.-W.</creator><general>International Union of Crystallography</general><scope>5PM</scope></search><sort><creationdate>20080104</creationdate><title>Poly[hexaaquacopper(II) [di-μ3-sulfato-disodiate(I)]]</title><author>Wu, Wen ; Xie, J.-M. ; Xie, D.-P. ; Xuan, Y.-W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmedcentral_primary_oai_pubmedcentral_nih_gov_29603203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Inorganic Papers</topic><toplevel>online_resources</toplevel><creatorcontrib>Wu, Wen</creatorcontrib><creatorcontrib>Xie, J.-M.</creatorcontrib><creatorcontrib>Xie, D.-P.</creatorcontrib><creatorcontrib>Xuan, Y.-W.</creatorcontrib><collection>PubMed Central (Full Participant titles)</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Wen</au><au>Xie, J.-M.</au><au>Xie, D.-P.</au><au>Xuan, Y.-W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly[hexaaquacopper(II) [di-μ3-sulfato-disodiate(I)]]</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2008-01-04</date><risdate>2008</risdate><volume>64</volume><issue>Pt 2</issue><spage>i7</spage><epage>i7</epage><pages>i7-i7</pages><eissn>1600-5368</eissn><abstract>The title compound, {[Cu(H
2
O)
6
][Na
2
(SO
4
)
2
]}
n
, has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (
). The Na atom is coordinated by five O atoms of four sulfates [Na—O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetradentate mode.</abstract><pub>International Union of Crystallography</pub><pmid>21201248</pmid><doi>10.1107/S1600536807067608</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1600-5368 |
| ispartof | Acta crystallographica. Section E, Structure reports online, 2008-01, Vol.64 (Pt 2), p.i7-i7 |
| issn | 1600-5368 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2960320 |
| source | DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Inorganic Papers |
| title | Poly[hexaaquacopper(II) [di-μ3-sulfato-disodiate(I)]] |
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