Poly[hexaaquacopper(II) [di-μ3-sulfato-disodiate(I)]]
The title compound, {[Cu(H 2 O) 6 ][Na 2 (SO 4 ) 2 ]} n , has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a spe...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-01, Vol.64 (Pt 2), p.i7-i7 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The title compound, {[Cu(H
2
O)
6
][Na
2
(SO
4
)
2
]}
n
, has been prepared under mild hydrothermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (
). The Na atom is coordinated by five O atoms of four sulfates [Na—O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetradentate mode. |
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| ISSN: | 1600-5368 |
| DOI: | 10.1107/S1600536807067608 |