Triphen-yl(tetra-hydro-furan)-aluminium(III)

Triphen-yl(tetra-hydro-furan)-aluminium(III)

In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetra-hedral geometry. The C-Al-C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O-Al-C angles, which range from 103.39 (7) to 103.90 (6)°. The tetra-hydro-furan ring adopts an envelope conformation....

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-10, Vol.64 (Pt 11), p.m1381-m1381
Hauptverfasser: Chen, Chi-Ren, Gau, Han-Mou
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
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Beschreibung
Zusammenfassung:In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetra-hedral geometry. The C-Al-C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O-Al-C angles, which range from 103.39 (7) to 103.90 (6)°. The tetra-hydro-furan ring adopts an envelope conformation. The crystal packing is stabilized by C-H⋯π inter-actions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808032091