catena-Poly[[[diaqua-iron(II)]-μ-pyrazine-2,3-dicarboxyl-ato] dihydrate]

The crystal structure of the title compound, {[Fe(C(6)H(2)N(2)O(4))(H(2)O)(2)]·2H(2)O}(n), was synthesized by a diffusion method. It has a one-dimensional polymeric chain structure and the chains are further connected into a three-dimensional structure by hydrogen bonds. The Fe(II) ion has a distort...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-12, Vol.64 (Pt 1), p.m104-m104
Hauptverfasser: Xu, Haiyun, Ma, Huailing, Xu, Maotian, Zhao, Wenxian, Guo, Baoguo
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal structure of the title compound, {[Fe(C(6)H(2)N(2)O(4))(H(2)O)(2)]·2H(2)O}(n), was synthesized by a diffusion method. It has a one-dimensional polymeric chain structure and the chains are further connected into a three-dimensional structure by hydrogen bonds. The Fe(II) ion has a distorted octa-hedral coordination environment, with two N and two O atoms from the pyrazine-2,3-dicarboxyl-ate ligands in the equatorial plane and with two water mol-ecules in axial positions. The Fe atom lies on a crystallographic centre of symmetry and a twofold rotation axis passes through the pyrazine ring.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807064501