Hydrogen-bonding patterns in two aroylthiocarbamates and two aroylimidothiocarbonates
In O -ethyl N -benzoylthiocarbamate, C 10 H 11 NO 2 S, the molecules are linked into sheets by a combination of two-centre N—H⋯O and C—H⋯S hydrogen bonds and a three-centre C—H⋯(O,S) hydrogen bond. A combination of two-centre N—H⋯O and C—H⋯O hydrogen bonds links the molecules of O -ethyl N -(4-m...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2010-02, Vol.66 (Pt 3), p.o141-o146 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | In
O
-ethyl
N
-benzoylthiocarbamate, C
10
H
11
NO
2
S, the molecules are linked into sheets by a combination of two-centre N—H⋯O and C—H⋯S hydrogen bonds and a three-centre C—H⋯(O,S) hydrogen bond. A combination of two-centre N—H⋯O and C—H⋯O hydrogen bonds links the molecules of
O
-ethyl
N
-(4-methylbenzoyl)thiocarbamate, C
11
H
13
NO
2
S, into chains of rings, which are linked into sheets by an aromatic π–π stacking interaction. In
O
,
S
-diethyl
N
-(4-methylbenzoyl)imidothiocarbonate, C
13
H
17
NO
2
S, pairs of molecules are linked into centrosymmetric dimers by pairs of symmetry-related C—H⋯π(arene) hydrogen bonds, while the molecules of
O
,
S
-diethyl
N
-(4-chlorobenzoyl)imidothiocarbonate, C
12
H
14
ClNO
2
S, are linked by a single C—H⋯O hydrogen bond into simple chains, pairs of which are linked by an aromatic π–π stacking interaction to form a ladder-type structure. |
|---|---|
| ISSN: | 0108-2701 1600-5759 |
| DOI: | 10.1107/S0108270110005032 |