Total Synthesis of the Originally Assigned Structure of Vannusal B

The truth is out there: The chase for the originally assigned structure of vannusal B (see structural formula) by total synthesis ended successfully, but created a new puzzle, that of the true structure of this intriguing marine natural product.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-01, Vol.47 (45), p.8605-8610
Hauptverfasser:	Nicolaou, K.C, Zhang, Hongjun, Ortiz, Adrian, Dagneau, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Animals Crystallography, X-Ray Cyclization Euplotes - chemistry Models, Molecular Molecular Conformation natural products samarium diiodide Spiro Compounds - chemical synthesis Spiro Compounds - chemistry Stereoisomerism total synthesis vannusals A and B
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Beschreibung
Zusammenfassung:	The truth is out there: The chase for the originally assigned structure of vannusal B (see structural formula) by total synthesis ended successfully, but created a new puzzle, that of the true structure of this intriguing marine natural product.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200804228