Enantioselective synthesis of Bakuchiol using diazosulfonate C–H insertion to install the quaternary center

Enantioselective synthesis of Bakuchiol using diazosulfonate C–H insertion to install the quaternary center

Bakuchiol was prepared from commercial (−)-citronellol using the diazosulfonate C–H insertion to control the regioselectivity and install the quaternary center. Bakuchiol was prepared from commercial (−)-citronellol using the diazosulfonate C–H insertion to control the regioselectivity and install t...

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Veröffentlicht in:Tetrahedron letters 2009-12, Vol.50 (50), p.6963-6964
Hauptverfasser: Bequette, Joseph P., Jungong, Christian S., Novikov, Alexei V.
Format: Artikel
Sprache:eng
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Zusammenfassung:Bakuchiol was prepared from commercial (−)-citronellol using the diazosulfonate C–H insertion to control the regioselectivity and install the quaternary center. Bakuchiol was prepared from commercial (−)-citronellol using the diazosulfonate C–H insertion to control the regioselectivity and install the quaternary center.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2009.09.147