Rapid Assembly of Vinigrol’s Unique Carbocyclic Skeleton

Rapid Assembly of Vinigrol’s Unique Carbocyclic Skeleton

Detailed in this account are our efforts toward the total synthesis of vinigrol. A highly expedient and convergent synthetic approach made possible by the use of a strategic oxidative dearomatization reaction coupled with a series of ensuing substrate controlled transformations is discussed.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2009-10, Vol.11 (20), p.4492-4495
Hauptverfasser: Morton, Jason G. M, Draghici, Cristian, Kwon, Laura D, Njardarson, Jon T
Format: Artikel
Sprache:eng
Schlagworte:
Cyclization
Diterpenes - chemical synthesis
Diterpenes - chemistry
Kinetics
Pyrogallol - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Detailed in this account are our efforts toward the total synthesis of vinigrol. A highly expedient and convergent synthetic approach made possible by the use of a strategic oxidative dearomatization reaction coupled with a series of ensuing substrate controlled transformations is discussed.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol901519k