Conversion of Allylic Alcohols to Stereodefined Trisubstituted Alkenes: A Complimentary Process to the Claisen Rearrangement
A stereoselective method for the conversion of allylic alcohols to ( Z )-trisubstituted alkenes is presented. Overall, the reaction sequence described is stereochemically complimentary to related Claisen rearrangement reactions – processes that typically deliver the stereoisomeric trisubstituted alk...
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| Veröffentlicht in: | Journal of the American Chemical Society 2008-12, Vol.130 (50), p.16870-16872 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A stereoselective method for the conversion of allylic alcohols to (
Z
)-trisubstituted alkenes is presented. Overall, the reaction sequence described is stereochemically complimentary to related Claisen rearrangement reactions – processes that typically deliver the stereoisomeric trisubstituted alkene containing products. |
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| ISSN: | 0002-7863 1520-5126 |
| DOI: | 10.1021/ja8074242 |