Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes

Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes

The first highly Z- and enantioselective class of ring-opening/cross-metathesis reactions is presented. Transformations are promoted in the presence of 98:98:

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Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2009-03, Vol.131 (11), p.3844-3845
Hauptverfasser: Ibrahem, Ismail, Yu, Miao, Schrock, Richard R, Hoveyda, Amir H
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Catalysis
Cyclization
Molybdenum
Organometallic Compounds
Pyrans - chemical synthesis
Stereoisomerism
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Beschreibung
Zusammenfassung:The first highly Z- and enantioselective class of ring-opening/cross-metathesis reactions is presented. Transformations are promoted in the presence of 98:98:
ISSN:0002-7863
1520-5126
DOI:10.1021/ja900097n