Bis{( S )-(-)- N -[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κ N }di-chlorido-palladium(II)
The Pd complex bis-{( )-(-)- -[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ }di-chlorido-palladium(II), [PdCl (C H NO) ], crystallizes in the monoclinic Sohncke space group 2 with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slight...
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Veröffentlicht in: | IUCrData 2024-07, Vol.9 (Pt 7), p.x240555 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | The Pd
complex bis-{(
)-(-)-
-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κ
}di-chlorido-palladium(II), [PdCl
(C
H
NO)
], crystallizes in the monoclinic Sohncke space group
2
with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd-Cl and Pd-N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314624005558 |