Stereoselective Synthesis of Either Exo- or Endo-3‑Azabicyclo[3.1.0]hexane-6-carboxylates by Dirhodium(II)-Catalyzed Cyclopropanation with Ethyl Diazoacetate under Low Catalyst Loadings

Stereoselective Synthesis of Either Exo- or Endo-3‑Azabicyclo[3.1.0]hexane-6-carboxylates by Dirhodium(II)-Catalyzed Cyclopropanation with Ethyl Diazoacetate under Low Catalyst Loadings

Although cyclopropanation with donor/acceptor carbenes can be conducted under low catalyst loadings (

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2024-04, Vol.26 (14), p.2832-2836
Hauptverfasser: Nguyen, Terrence-Thang H., Navarro, Antonio, Ruble, J. Craig, Davies, Huw M. L.
Format: Artikel
Sprache:eng
Schlagworte:
carbenes
catalysts
chromatography
diastereoselectivity
hydrolysis
Letter
stereoselective synthesis
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Zusammenfassung:Although cyclopropanation with donor/acceptor carbenes can be conducted under low catalyst loadings (
ISSN:1523-7060
1523-7052
1523-7052
DOI:10.1021/acs.orglett.3c03652