Carbon‐Carbon Bond Formation from Carbon Monoxide and Hydride: The Role of Metal Formyl Intermediates

Carbon‐Carbon Bond Formation from Carbon Monoxide and Hydride: The Role of Metal Formyl Intermediates

Current examples of carbon chain production from metal formyl intermediates with homogeneous metal complexes are described in this Minireview. Mechanistic aspects of these reactions as well as the challenges and opportunities in using this understanding to develop new reactions of CO and H2 are also...

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Veröffentlicht in:Angewandte Chemie International Edition 2023-05, Vol.62 (19), p.e202219203-n/a
Hauptverfasser: Parr, Joseph M., Crimmin, Mark R.
Format: Artikel
Sprache:eng
Schlagworte:
Carbon Monoxide
Coordination compounds
Ethenediolate
Fischer Tropsch
Homologation
Intermediates
Metal complexes
Metal Formyl
Minireview
Minireviews
Molecular chains
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Zusammenfassung:Current examples of carbon chain production from metal formyl intermediates with homogeneous metal complexes are described in this Minireview. Mechanistic aspects of these reactions as well as the challenges and opportunities in using this understanding to develop new reactions of CO and H2 are also discussed. In this Minireview, we summarise the current examples of carbon chain production from metal formyl intermediates with homogeneous metal complexes. We discuss the mechanistic aspects of these reactions and the challenges and opportunities in using this understanding to develop new reactions of CO and H2.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202219203