Oxygen-Containing Quaternary Phosphonium Salts (oxy-QPSs): Synthesis, Properties, and Cellulose Dissolution

In the present study, the synthesis of oxygen-containing quaternary phosphonium salts (oxy-QPSs) was described. Within this work, structure–property relationships of oxy-QPSs were estimated by systematic analysis of physical–chemical properties. The influence of the oxygen-containing substituent was...

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Veröffentlicht in:Polymers 2023-10, Vol.15 (20), p.4097
Hauptverfasser: Arkhipova, Daria M., Ermolaev, Vadim V., Baembitova, Gulnaz R., Samigullina, Aida I., Lyubina, Anna P., Voloshina, Alexandra D.
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Sprache:eng
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Zusammenfassung:In the present study, the synthesis of oxygen-containing quaternary phosphonium salts (oxy-QPSs) was described. Within this work, structure–property relationships of oxy-QPSs were estimated by systematic analysis of physical–chemical properties. The influence of the oxygen-containing substituent was examined by comparing the properties of oxy-QPSs in homology series as well as with phosphonium analog-included alkyl side chains. The crystal structure analysis showed that the oxygen introduction influences the conformation of the side chain of the oxy-QPS. It was found that oxy-QPSs, using an aprotic co-solvent, dimethylsulfoxide (DMSO), can dissolve microcrystalline cellulose. The cellulose dissolution in oxy-QPSs appeared to be dependent on the functional group in the cation and anion nature. For the selected conditions, dissolution of up to 5 wt% of cellulose was observed. The antimicrobial activity of oxy-QPSs under study was expected to be low. The biocompatibility of oxy-QPSs with fermentative microbes was tested on non-pathogenic Saccharomyces cerevisiae, Lactobacillus plantarum, and Bacillus subtilis. This reliably allows one to safely address the combined biomass destruction and enzyme hydrolysis processes in one pot.
ISSN:2073-4360
2073-4360
DOI:10.3390/polym15204097