High-performance Vo-ZnO/ZnS benefiting nanoarchitectonics from the synergism between defect engineering and surface engineering for photoelectrochemical glucose sensors

In this study, a ZnO/ZnS nanocluster heterojunction photoelectrode rich in surface oxygen defects (Vo-ZnO/ZnS) was prepared by applying a simple in situ anion substitution and nitrogen atmosphere annealing method. The synergism between defect and surface engineering significantly improved the photoc...

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Veröffentlicht in:RSC advances 2023-06, Vol.13 (29), p.19782-19788
Hauptverfasser: Xu, Yongtao, Yan, Bingdong, Lai, Caiyan, Wang, Mingyu, Cao, Yang, Tu, Jinchun, Chen, Delun, Liu, Youbin, Wu, Qiang
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Sprache:eng
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Zusammenfassung:In this study, a ZnO/ZnS nanocluster heterojunction photoelectrode rich in surface oxygen defects (Vo-ZnO/ZnS) was prepared by applying a simple in situ anion substitution and nitrogen atmosphere annealing method. The synergism between defect and surface engineering significantly improved the photocatalysts. Given this synergism, Vo-ZnO/ZnS was endowed with a long carrier lifetime, narrow band gap, high carrier density, and high performance toward electron transfer under light conditions. Thus, Vo-ZnO/ZnS had three times the photocurrent density of ZnO under light illumination. To further evaluate its advantages in the field of photoelectric bioassay, Vo-ZnO/ZnS was applied as the photocathode of photoelectric sensor system for glucose detection. Vo-ZnO/ZnS showed excellent performance in glucose detection in various aspects, including a low detection limit, high detection sensitivity, and a wide detection range. In this study, a ZnO/ZnS nanocluster heterojunction photoelectrode rich in surface oxygen defects (Vo-ZnO/ZnS) was prepared by applying a simple in situ anion substitution and nitrogen atmosphere annealing method.
ISSN:2046-2069
2046-2069
DOI:10.1039/d3ra02869k