Polymorphic structures of 3-phenyl-1H-1,3-benzo-diazol-2(3H)-one
The two polymorphic structures of 3-phenyl-1 H -1,3-benzodiazol-2(3 H )-one ( I and II ) exhibit identical bond distances and angles except for the C—N—C—C torsion angle between the benzimidazolone backbone and the phenyl substituent, which has an effect on the crystal packing and supramolecular f...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-05, Vol.79 (Pt 6), p.534-537 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The two polymorphic structures of 3-phenyl-1
H
-1,3-benzodiazol-2(3
H
)-one (
I
and
II
) exhibit identical bond distances and angles except for the C—N—C—C torsion angle between the benzimidazolone backbone and the phenyl substituent, which has an effect on the crystal packing and supramolecular features. The structure of
I
contains a stronger C=O⋯H—N hydrogen-bonding interaction and a weaker π–π interaction between adjacent bezimidazolone moieties in comparison to
II
.
The polymorphic structures (
I
and
II
) of 3-phenyl-1
H
-1,3-benzodiazol-2(3
H
)-one, C
13
H
10
N
2
O, acquired from pentane diffusion into the solution in THF, are reported. The structures show negligible differences in bond distances and angles, but the C—N—C—C torsion angles between the backbone and the phenyl substituent, 123.02 (15)° for
I
and 137.18 (11)° for
II
, are different. Compound
I
features a stronger C=O⋯H—N hydrogen bond than that in
II
, while the structure of
II
exhibits a stronger π–π interaction than in
I
, as confirmed by the shorter intercentroid distance [3.3257 (8) Å in
II
in comparison to 3.6862 (7) Å in
I
]. Overall, the supramolecular interactions of
I
and
II
are distinct, presumably originating from the variation in the dihedral angle. |
---|---|
ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989023003961 |