Evaluation of the Effect of Precursor NMC622@TiO 2 Core-Shell Powders Using a Prelithiated Anode from Fig Seeds: Spotlight on Li-ion Full-Cell Performance
In this study, innovative electrode materials for lithium-ion batteries (LIBs) were developed and characterized, demonstrating significant performance enhancements. Initially, NMC622@TiO was synthesized using a wet-chemical method with titanium(IV) ethoxide as the Ti source. Advanced structural inve...
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Veröffentlicht in: | ACS applied materials & interfaces 2024-12 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this study, innovative electrode materials for lithium-ion batteries (LIBs) were developed and characterized, demonstrating significant performance enhancements. Initially, NMC622@TiO
was synthesized using a wet-chemical method with titanium(IV) ethoxide as the Ti source. Advanced structural investigations confirmed the successful formation of a core@shell structure with negligible cation mixing (Li
/Ni
) at the NMC622 surface, contributing to enhanced electrochemical performance. Subsequently, carbon-based anode materials were produced from biomass, specifically fig seeds, and subjected to high-temperature heat treatment. The resulting powders exhibited dominant graphitic properties, evidenced by a Raman
/
ratio of 0.5. Electrochemical evaluations of both electrode materials were conducted using half-cell configurations. The optimization of the TiO
coating process was assessed through half-cell performance metrics and diffusion rates calculated from galvanostatic intermittent titration technique (GITT) experiments. The final phase focused on full-cell design, employing a prelithiation strategy for anodes using a direct contact technique. Optimization of the prelithiation process led to the assembly of full cells combining NMC622/prelithiated fig-seed anodes and NMC622@TiO
/prelithiated fig-seed anodes. The results revealed that TiO
-coated NMC622, paired with prelithiated carbon anodes derived from fig seeds, delivered superior performance compared to uncoated NMC622 full cells. This study underscores the potential of biomass-derived carbon anodes and TiO
coatings in enhancing the efficiency and performance of LIBs. |
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ISSN: | 1944-8252 |