Porous alumina nanosheet-supported asymmetric platinum clusters for efficient diboration of alkynes

Precisely designing asymmetrical structures is an effective strategy to optimize the performance of metallic catalysts. Asymmetric Pt clusters were attached to defect-rich porous alumina nanosheets (Pt clu/dp-Al 2 O 3 ) using a pyrolysis technique coupled with wet impregnation. These Pt-functionalized nanosheets feature a high concentration of active sites, demonstrating remarkable cycling performance and catalytic activity in alkyne diboration. The conversion yield and selectivity can reach up to 97% and 95%, correspondingly. Precisely designing asymmetrical structures is an effective strategy to optimize the performance of metallic catalysts.