A regulation strategy of self-assembly molecules for achieving efficient inverted perovskite solar cells

Self-assembled monolayers (SAMs) have been successfully employed to enhance the efficiency of inverted perovskite solar cells (PSCs) and perovskite/silicon tandem solar cells due to their facile low-temperature processing and superior device performance. Nevertheless, depositing uniform and dense SAMs with high surface coverage on metal oxide substrates remains a critical challenge. In this work, we propose a holistic strategy to construct composite hole transport layers (HTLs) by co-adsorbing mixed SAMs (MeO-2PACz and 2PACz) onto the surface of the H 2 O 2 -modified NiO x layer. The results demonstrate that the conductivity of the NiO x bulk phase is enhanced due to the H 2 O 2 modification, thereby facilitating carrier transport. Furthermore, the hydroxyl-rich NiO x surface promotes uniform and dense adsorption of mixed SAM molecules while enhancing their anchoring stability. In addition, the energy level alignment at the interface is improved due to the utilization of mixed SAMs in an optimized ratio. Furthermore, the perovskite film crystal growth is facilitated by the uniform and dense composite HTLs. As a result, the power conversion efficiency of PSCs based on composite HTLs is boosted from 22.26% to 23.16%, along with enhanced operational stability. This work highlights the importance of designing and constructing NiO x /SAM composite HTLs as an effective strategy for enhancing both the performance and stability of inverted PSCs. Hydroxyl-rich NiO x and mixed self-assembled monolayer (SAM) based composite hole transport layers were constructed for achieving efficient p-i-n perovskite solar cells.