Complexation with pagoda[]arene ( = 4, 5) protects ferrocenium from oxidation

Complexation with pagoda[]arene ( = 4, 5) protects ferrocenium from oxidation

The complexation behaviors of pagoda[ n ]arenes ( n = 4, 5) with ferrocene, ferrocenium and analogues cobaltocenium were studied. The inclusion complexes of pagoda[ n ]arenes can protect ferrocenium from oxidation in organic solvents and improve the stability and oxygen resistance of ferrocenium. Th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (48), p.7431-7434
Hauptverfasser: Chen, Gui-Hua, Duan, Yi-Meng, Li, Ying, Han, Xiao-Ni, Wang, Kun-Peng, Hu, Zhi-Qiang, Chen, Chuan-Feng
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Complexation
Inclusion complexes
Oxidation resistance
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Zusammenfassung:The complexation behaviors of pagoda[ n ]arenes ( n = 4, 5) with ferrocene, ferrocenium and analogues cobaltocenium were studied. The inclusion complexes of pagoda[ n ]arenes can protect ferrocenium from oxidation in organic solvents and improve the stability and oxygen resistance of ferrocenium. The inclusion complexes of pagoda[ n ]arenes with ferrocenium can prevent the destruction of oxygen to ferrocenium in organic solvent and improve the stability and oxygen resistance.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc01202f