A Zr-added Dawson-type poly(polyoxometalate)
A novel Zr-added trimer, [H 2 N(CH 3 ) 2 ] 10 H 14 [(Zr 2 P 2 W 16 O 61 ) 3 ]·7H 2 O ( 1 ), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-01, Vol.52 (4), p.857-861 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Li, Hai-Lou Lian, Chen Yang, Guo-Yu |
| description | A novel Zr-added trimer, [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O (
1
), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P
2
W
16
O
60
]
14−
fragment, which assembles with Zr
4+
ions to form a cyclic trimer. Furthermore,
1
as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.
An unprecedented Zr-added poly(POM), [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied. |
| doi_str_mv | 10.1039/d2dt03820j |
| format | Article |
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2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O (
1
), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P
2
W
16
O
60
]
14−
fragment, which assembles with Zr
4+
ions to form a cyclic trimer. Furthermore,
1
as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.
An unprecedented Zr-added poly(POM), [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt03820j</identifier><identifier>PMID: 36602105</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Anions ; Mustard Gas ; Polyoxometallates ; Trimers ; Zirconium</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-01, Vol.52 (4), p.857-861</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-1ed758c9719c5a57c4f9ff0f2be5a6190fff327168703fbbca7e61758fa9882a3</citedby><cites>FETCH-LOGICAL-c337t-1ed758c9719c5a57c4f9ff0f2be5a6190fff327168703fbbca7e61758fa9882a3</cites><orcidid>0000-0002-0911-2805</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27933,27934</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36602105$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Hai-Lou</creatorcontrib><creatorcontrib>Lian, Chen</creatorcontrib><creatorcontrib>Yang, Guo-Yu</creatorcontrib><title>A Zr-added Dawson-type poly(polyoxometalate)</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>A novel Zr-added trimer, [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O (
1
), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P
2
W
16
O
60
]
14−
fragment, which assembles with Zr
4+
ions to form a cyclic trimer. Furthermore,
1
as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.
An unprecedented Zr-added poly(POM), [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied.</description><subject>Anions</subject><subject>Mustard Gas</subject><subject>Polyoxometallates</subject><subject>Trimers</subject><subject>Zirconium</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LAzEQhoMotlYv3pWCFxVXJ5Mm2RxL6ycFL_XiZcnmAyxtsya7aP-9W1vrZWZgnnkHHkJOKdxSYOrOoq2B5QizPdKlAykzhWywv5tRdMhRSjMAROB4SDpMCEAKvEtuhv33mGlrne2P9VcKy6xeVa5fhfnqcl3Cd1i4Ws917a6OyYHX8-ROtr1H3h7up6OnbPL6-DwaTjLDmKwz6qzkuVGSKsM1l2bglffgsXRcC6rAe89QUpFLYL4sjZZO0PbEa5XnqFmPXGxyqxg-G5fqYhaauGxfFihFLjiVQrbU9YYyMaQUnS-q-LHQcVVQKNZiijGOp79iXlr4fBvZlAtnd-ifiRY42wAxmd323yz7AQ2_Ze4</recordid><startdate>20230124</startdate><enddate>20230124</enddate><creator>Li, Hai-Lou</creator><creator>Lian, Chen</creator><creator>Yang, Guo-Yu</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-0911-2805</orcidid></search><sort><creationdate>20230124</creationdate><title>A Zr-added Dawson-type poly(polyoxometalate)</title><author>Li, Hai-Lou ; Lian, Chen ; Yang, Guo-Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-1ed758c9719c5a57c4f9ff0f2be5a6190fff327168703fbbca7e61758fa9882a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anions</topic><topic>Mustard Gas</topic><topic>Polyoxometallates</topic><topic>Trimers</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Hai-Lou</creatorcontrib><creatorcontrib>Lian, Chen</creatorcontrib><creatorcontrib>Yang, Guo-Yu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Hai-Lou</au><au>Lian, Chen</au><au>Yang, Guo-Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Zr-added Dawson-type poly(polyoxometalate)</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2023-01-24</date><risdate>2023</risdate><volume>52</volume><issue>4</issue><spage>857</spage><epage>861</epage><pages>857-861</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A novel Zr-added trimer, [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O (
1
), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P
2
W
16
O
60
]
14−
fragment, which assembles with Zr
4+
ions to form a cyclic trimer. Furthermore,
1
as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.
An unprecedented Zr-added poly(POM), [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>36602105</pmid><doi>10.1039/d2dt03820j</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-0911-2805</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-01, Vol.52 (4), p.857-861 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_pubmed_primary_36602105 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Anions Mustard Gas Polyoxometallates Trimers Zirconium |
| title | A Zr-added Dawson-type poly(polyoxometalate) |
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