A Zr-added Dawson-type poly(polyoxometalate)
A novel Zr-added trimer, [H 2 N(CH 3 ) 2 ] 10 H 14 [(Zr 2 P 2 W 16 O 61 ) 3 ]·7H 2 O ( 1 ), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-01, Vol.52 (4), p.857-861 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A novel Zr-added trimer, [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O (
1
), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P
2
W
16
O
60
]
14−
fragment, which assembles with Zr
4+
ions to form a cyclic trimer. Furthermore,
1
as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES.
An unprecedented Zr-added poly(POM), [H
2
N(CH
3
)
2
]
10
H
14
[(Zr
2
P
2
W
16
O
61
)
3
]·7H
2
O, has been made under hydrothermal conditions, and as a heterogeneous catalyst, its selective oxidative degradation of a sulfur mustard simulant CEES has further been studied. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/d2dt03820j |