Construction of direct FeMoO 4 /g-C 3 N 4 -2D/2D Z-scheme heterojunction with enhanced photocatalytic treatment of textile wastewater to eliminate the toxic effect in marine environment
A novel FeMoO /g-C N -2D/2D Z-scheme heterojunction photocatalyst was prepared via wet chemical method. The observed structural morphology of FeMoO /g-C N reveals the 2D-iron molybdate (FeMoO ) nanoplates compiled with the 2D-graphitic carbon nitride (g-C N ) nanosheets like structure. The photocata...
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Veröffentlicht in: | Chemosphere (Oxford) 2023-02, Vol.313, p.137552 |
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Hauptverfasser: | , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | A novel FeMoO
/g-C
N
-2D/2D Z-scheme heterojunction photocatalyst was prepared via wet chemical method. The observed structural morphology of FeMoO
/g-C
N
reveals the 2D-iron molybdate (FeMoO
) nanoplates compiled with the 2D-graphitic carbon nitride (g-C
N
) nanosheets like structure. The photocatalytic activity of the g-C
N
, FeMoO
, and FeMoO
/g-C
N
composites were studied via the degradation of Rhodamine B (RhB) as targeted textile dye under visible light irradiation (VLI). The optimal FeMoO
/g-C
N
(1:3 ratio of g-C
N
and FeMoO
) composite show an enhanced degradation performance with rate constant value of 0.02226 min
and good stability even after three cycles. Thus, the h+ and O
are the key radicals in the degradation of RhB under VLI. It is proposed that the FeMoO
/g-C
N
Z-scheme heterojunction effectively enhances the transfer and separation ability of e
/h
pairs, by the way increasing the photocatalytic efficiency towards the RhB degradation. Thus, the newly constructed Z-scheme FeMoO
/g-C
N
heterojunction photocatalyst is a promising material for the remediation of wastewater relevant to elimination of toxic effect in marine environment. |
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ISSN: | 1879-1298 |
DOI: | 10.1016/j.chemosphere.2022.137552 |