Construction of direct FeMoO 4 /g-C 3 N 4 -2D/2D Z-scheme heterojunction with enhanced photocatalytic treatment of textile wastewater to eliminate the toxic effect in marine environment

A novel FeMoO /g-C N -2D/2D Z-scheme heterojunction photocatalyst was prepared via wet chemical method. The observed structural morphology of FeMoO /g-C N reveals the 2D-iron molybdate (FeMoO ) nanoplates compiled with the 2D-graphitic carbon nitride (g-C N ) nanosheets like structure. The photocata...

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Veröffentlicht in:Chemosphere (Oxford) 2023-02, Vol.313, p.137552
Hauptverfasser: Arumugam, Swaminathan, Bavani, Thirugnanam, Selvaraj, Manickam, Al-Shehri, Badria M, Preeyanghaa, Mani, Jung, Sieon, Theerthagiri, Jayaraman, Neppolian, Bernaurdshaw, Murugesan, Sepperumal, Madhavan, Jagannathan, Choi, Myong Yong
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Sprache:eng
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Zusammenfassung:A novel FeMoO /g-C N -2D/2D Z-scheme heterojunction photocatalyst was prepared via wet chemical method. The observed structural morphology of FeMoO /g-C N reveals the 2D-iron molybdate (FeMoO ) nanoplates compiled with the 2D-graphitic carbon nitride (g-C N ) nanosheets like structure. The photocatalytic activity of the g-C N , FeMoO , and FeMoO /g-C N composites were studied via the degradation of Rhodamine B (RhB) as targeted textile dye under visible light irradiation (VLI). The optimal FeMoO /g-C N (1:3 ratio of g-C N and FeMoO ) composite show an enhanced degradation performance with rate constant value of 0.02226 min and good stability even after three cycles. Thus, the h+ and O are the key radicals in the degradation of RhB under VLI. It is proposed that the FeMoO /g-C N Z-scheme heterojunction effectively enhances the transfer and separation ability of e /h  pairs, by the way increasing the photocatalytic efficiency towards the RhB degradation. Thus, the newly constructed Z-scheme FeMoO /g-C N heterojunction photocatalyst is a promising material for the remediation of wastewater relevant to elimination of toxic effect in marine environment.
ISSN:1879-1298
DOI:10.1016/j.chemosphere.2022.137552