One-pot reductive amination of carbonyl compounds with nitro compounds over a Ni/NiO composite

Easily prepared Ni/NiO acts as a heterogeneous catalyst for the one-pot reductive amination of carbonyl compounds with nitroarenes to afford secondary amines with H 2 as a hydride source. This catalytic system does not require a special technique to avoid air-exposure, in contrast to the common hete...

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Veröffentlicht in:RSC advances 2020-09, Vol.1 (54), p.32296-323
Hauptverfasser: Kita, Yusuke, Kai, Sayaka, Supriadi Rustad, Lesandre Binti, Kamata, Keigo, Hara, Michikazu
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Sprache:eng
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Zusammenfassung:Easily prepared Ni/NiO acts as a heterogeneous catalyst for the one-pot reductive amination of carbonyl compounds with nitroarenes to afford secondary amines with H 2 as a hydride source. This catalytic system does not require a special technique to avoid air-exposure, in contrast to the common heterogeneous Ni catalysts. Easy-to-prepare Ni/NiO acts as an efficient heterogeneous catalyst for one-pot reductive amination of carbonyl compounds with nitroarenes.
ISSN:2046-2069
2046-2069
DOI:10.1039/d0ra06937j