Fabrication of chemically stable hydrogen- and niobium-codoped ZnO transparent conductive films

H- and Nb-doped ZnO (HNZO) thin films were fabricated on glass substrates with radio frequency magnetron sputtering. The effect of the flow rate of H 2 has been investigated by analyzing the structural, optical, and electrical properties. The incorporation of H during the deposition of Nb-incorporat...

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Veröffentlicht in:RSC advances 2019-04, Vol.9 (22), p.12681-12688
Hauptverfasser: Han, Bing, Song, Jianmin, Li, Junjie, Guo, Yajuan, Dai, Binting, Meng, Xudong, Song, Weiye, Yang, Fu, Wang, Yanfeng
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Sprache:eng
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Zusammenfassung:H- and Nb-doped ZnO (HNZO) thin films were fabricated on glass substrates with radio frequency magnetron sputtering. The effect of the flow rate of H 2 has been investigated by analyzing the structural, optical, and electrical properties. The incorporation of H during the deposition of Nb-incorporated ZnO films significantly improved their crystallinity, conductivity, and transmittance. The crystallites of the HNZO films were preferentially oriented in the c -axis direction; the films possess high transmittance (approximately 85%) in the visible and near-infrared regions (400 to 1400 nm). The lowest room-temperature resistivity of the HNZO films was measured as 1.28 × 10 −3 Ω cm. Such optical and electrical properties along with the remarkable chemical stability of the HNZO films make them a promising candidate for applications in solar cells. H- and Nb-doped ZnO (HNZO) thin films were fabricated on glass substrates with radio frequency magnetron sputtering.
ISSN:2046-2069
2046-2069
DOI:10.1039/c9ra01231a