Detecting chirality in mixtures using nanosecond photoelectron circular dichroism

We report chirality detection of structural isomers in a gas phase mixture using nanosecond photoelectron circular dichroism (PECD). Combining pulsed molecular beams with high-resolution resonance enhanced multi-photon ionization (REMPI) allows specific isolated transitions belonging to distinct com...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2022-02, Vol.24 (5), p.2758-2761
Hauptverfasser:	Ranecky, Simon T, Park, G. Barratt, Samartzis, Peter C, Giannakidis, Ioannis C, Schwarzer, Dirk, Senftleben, Arne, Baumert, Thomas, Schäfer, Tim
Format:	Artikel
Sprache:	eng
Schlagworte:	Chirality Dichroism Isomers Molecular beams Photoelectrons Vapor phases
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Zusammenfassung:	We report chirality detection of structural isomers in a gas phase mixture using nanosecond photoelectron circular dichroism (PECD). Combining pulsed molecular beams with high-resolution resonance enhanced multi-photon ionization (REMPI) allows specific isolated transitions belonging to distinct components in the mixture to be targeted. This article presents a new chirality detection method of structural isomers using nanosecond photoelectron circular dichroism (PECD).
ISSN:	1463-9076 1463-9084
DOI:	10.1039/d1cp05468f