The impact of temperature and unwanted impurities on slow compression of ice

For slowly compressed hexagonal ice pressure-induced amorphisation to high-density amorphous ice (HDA) takes place below and at 130 K, but polymorphic transformation to ice IX takes place at 140-170 K. Stable ice II only forms above 170 K. Ice IX impurities trigger ice IX growth even at 120 K. HDA a...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2021-12, Vol.24 (1), p.35-41
Hauptverfasser: Tonauer, Christina M, Bauer, Marion, Loerting, Thomas
Format: Artikel
Sprache:eng
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Zusammenfassung:For slowly compressed hexagonal ice pressure-induced amorphisation to high-density amorphous ice (HDA) takes place below and at 130 K, but polymorphic transformation to ice IX takes place at 140-170 K. Stable ice II only forms above 170 K. Ice IX impurities trigger ice IX growth even at 120 K. HDA and ice IX are equally long-lived, where both can be regarded as metastable phases. Slow compression of ice at 100 K usually results in pressure-amorphisation, unless there are ice IX seeds and temperature gradients.
ISSN:1463-9076
1463-9084
DOI:10.1039/d1cp03922a