Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes

Mechanically interlocked molecules can exhibit molecular chirality that arises due to the mechanical bond rather than covalent stereogenic units. Developing applications of such systems is made challenging by the absence of techniques for assigning the absolute configuration of products and methods...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-07, Vol.11 (32), p.8469-8475
Hauptverfasser:	Koenis, Mark A. J, Chibueze, C. S, Jinks, M. A, Nicu, Valentin P, Visscher, Lucas, Goldup, S. M, Buma, Wybren J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chirality Coupling (molecular) Dichroism Functional groups Oscillators Rotaxanes Shafts (machine elements) Spectrum analysis Stereoisomerism
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