Photo-Fries rearrangement in flow under aqueous micellar conditions
A flow edition of photo-Fries rearrangement for the synthesis of 2-acylphenols in an aqueous micellar medium has been described. We take advantage of a narrow channel reactor and micelle-induced confinement effect to refine both the efficiency and selectivity of the parent photoreaction. A combinati...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-12, Vol.56 (98), p.1547-15472 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | A flow edition of photo-Fries rearrangement for the synthesis of 2-acylphenols in an aqueous micellar medium has been described. We take advantage of a narrow channel reactor and micelle-induced confinement effect to refine both the efficiency and selectivity of the parent photoreaction.
A combination of an aqueous micellar medium and a flow reactor provides a green approach for refining the classic photo-Fries rearrangement. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/d0cc07331h |