Speed-dependent Voigt lineshape parameter database from dual frequency comb measurements at temperatures up to 1305 K. Part II: Argon-broadened H 2 O absorption, 6801-7188 cm -1

We report argon-broadened water vapor transition parameters and their temperature dependence based on measured spectra spanning 6801-7188 cm from a broad-bandwidth, high-resolution dual frequency comb spectrometer. The 25 collected spectra of 2% water vapor in argon ranged from 296 K to 1305 K with...

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Veröffentlicht in:Journal of quantitative spectroscopy & radiative transfer 2018-09, Vol.217, p.189
Hauptverfasser: Yang, Jinyu, Schroeder, Paul J, Cich, Matthew J, Giorgetta, Fabrizio R, Swann, William C, Coddington, Ian, Newbury, Nathan R, Drouin, Brian J, Rieker, Gregory B
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Sprache:eng
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Zusammenfassung:We report argon-broadened water vapor transition parameters and their temperature dependence based on measured spectra spanning 6801-7188 cm from a broad-bandwidth, high-resolution dual frequency comb spectrometer. The 25 collected spectra of 2% water vapor in argon ranged from 296 K to 1305 K with total pressure spanning 100 Torr to 600 Torr. A multispectrum fitting routine was used in conjunction with a quadratic speed-dependent Voigt profile to extract broadening and shift parameters, and a power-law temperature-dependence exponent for both. The measurements represent the first broad bandwidth, argon-broadened water vapor absorption study, and are an important step toward a foreign-gas-perturbed, high-temperature database developed using advanced lineshape profiles.
ISSN:0022-4073
DOI:10.1016/j.jqsrt.2018.05.040