Selective, High-Temperature O-2 Adsorption in Chemically Reduced, Redox-Active Iron-Pyrazolate Metal-Organic Frameworks

Selective, High-Temperature O-2 Adsorption in Chemically Reduced, Redox-Active Iron-Pyrazolate Metal-Organic Frameworks

Developing O-2-selective adsorbents that can produce high-purity oxygen from air remains a significant challenge. Here, we show that chemically reduced metal-organic framework materials of the type A(x)Fe(2)(bdp)(3) (A = Na+, K+; bdp(2-) = 1,4-benzenedipyrazolate; 0 < x

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Veröffentlicht in:Journal of the American Chemical Society 2020-08, Vol.142 (34), p.14627-14637
Hauptverfasser: Jaffe, Adam, Ziebel, Michael E., Halat, David M., Biggins, Naomi, Murphy, Ryan A., Chakarawet, Khetpakorn, Reimer, Jeffrey A., Long, Jeffrey R.
Format: Artikel
Sprache:eng
Schlagworte:
Adsorption
Chemistry
Chemistry, Multidisciplinary
Iron - chemistry
Metal-Organic Frameworks - chemistry
Oxidation-Reduction
Oxygen - chemistry
Particle Size
Physical Sciences
Pyrazoles - chemistry
Science & Technology
Surface Properties
Temperature
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Beschreibung
Zusammenfassung:Developing O-2-selective adsorbents that can produce high-purity oxygen from air remains a significant challenge. Here, we show that chemically reduced metal-organic framework materials of the type A(x)Fe(2)(bdp)(3) (A = Na+, K+; bdp(2-) = 1,4-benzenedipyrazolate; 0 < x
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.0c06570