Enhancing the activity of photocatalytic hydrogen evolution from CdSe quantum dots with a polyoxovanadate cluster

We report the improvement of photocatalytic proton reduction using molecular polyoxovanadate-alkoxide clusters as hole scavengers for CdSe quantum dots. The increased hydrogen production is explained by favorable charge interactions between reduced forms of the cluster and the charge on the quantum dots arising from the capping ligands. Adding metal-cluster hole scavengers enhances photocatalytic hydrogen production by quantum dots.