A 2-to-2′ 18-to-18′ doubly linked Ni() norcorrole dimer: an effectively conjugated antiaromatic dyad

A 2-to-2′ 18-to-18′ doubly linked Ni() norcorrole dimer: an effectively conjugated antiaromatic dyad

The synthesis and properties of a 2-to-2′ 18-to-18′ doubly linked Ni( ii ) norcorrole dimer are described. It adopts a highly planar structure, resulting in effective electronic interactions between the constituent norcorrole units. Nevertheless, each norcorrole unit exhibits substantial antiaromati...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-06, Vol.56 (5), p.6846-6849
Hauptverfasser: Liu, Si-Yu, Kawashima, Hiroyuki, Fukui, Norihito, Shinokubo, Hiroshi
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Crystallography
Dimers
Molecular structure
Planar structures
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container_title Chemical communications (Cambridge, England)
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creator Liu, Si-Yu
Kawashima, Hiroyuki
Fukui, Norihito
Shinokubo, Hiroshi
description The synthesis and properties of a 2-to-2′ 18-to-18′ doubly linked Ni( ii ) norcorrole dimer are described. It adopts a highly planar structure, resulting in effective electronic interactions between the constituent norcorrole units. Nevertheless, each norcorrole unit exhibits substantial antiaromaticity, which stands in sharp contrast to stacked norcorrole dimers. A fused norcorrole dimer has been synthesized in which each norcorrole unit exhibited distinct antiaromaticity.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Crystallography
Dimers
Molecular structure
Planar structures
title A 2-to-2′ 18-to-18′ doubly linked Ni() norcorrole dimer: an effectively conjugated antiaromatic dyad
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