A 2-to-2′ 18-to-18′ doubly linked Ni() norcorrole dimer: an effectively conjugated antiaromatic dyad
The synthesis and properties of a 2-to-2′ 18-to-18′ doubly linked Ni( ii ) norcorrole dimer are described. It adopts a highly planar structure, resulting in effective electronic interactions between the constituent norcorrole units. Nevertheless, each norcorrole unit exhibits substantial antiaromati...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-06, Vol.56 (5), p.6846-6849 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The synthesis and properties of a 2-to-2′ 18-to-18′ doubly linked Ni(
ii
) norcorrole dimer are described. It adopts a highly planar structure, resulting in effective electronic interactions between the constituent norcorrole units. Nevertheless, each norcorrole unit exhibits substantial antiaromaticity, which stands in sharp contrast to stacked norcorrole dimers.
A fused norcorrole dimer has been synthesized in which each norcorrole unit exhibited distinct antiaromaticity. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d0cc02543g |